Sean Bean played Alec Trevelyan in Goldeneye
From his Bio:
http://www.tiscali.co.uk/entertainment/film/biographies/sean_bean_biog/4
The part of Richard Sharpe, star of Bernard Cornwell's hit series of novels, was intended for Paul McGann, a success in The Monocled Mutineer. But McGann suffered a timely accident and in stepped Bean to take the role of the Napoleonic hero. First came Sharpe's Rifles and Sharpe's Eagle, in 1993. There would be a further three productions each year till 1997, each of them massively popular, making Sean one of the UK's most beloved TV personalities. The occasional injury was easy to bear - like the time Sean and Alice Krige (as the Marquesa Dorada) galloped down a hill and both fell off their horses into a shallow stream. The director thought it looked great, so he ignored their pain and embarrassment and left it in.
http://www.tiscali.co.uk/entertainment/film/biographies/sean_bean_biog/5
He cemented his rep as a particularly dastardly villain by shining as Alec Trevalyan, Agent 006, in Goldeneye. Could James Bond stop him from destroying London with a big nuclear pulsing thing?