Brad Sallows
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There are few sources of amusement greater than the relative handful of people in government and civil service offices trying to outguess and get inside the decision cycle of markets.
Turning carbon dioxide into fuel - using solar power
Submitted by News on 18 April 2007 - 12:20pm. Energy
Turning a greenhouse gas into a clean energy fuel is the Holy Grail of energy research. UC San Diego chemists have a prototype they think is an important milestone.
Their device captures energy from the sun, converts it to electrical energy and "splits" carbon dioxide into carbon monoxide (CO) and oxygen.
Obviously carbon monoxide in and of itself is not great either but millions of pounds of it are used each year to manufacture chemicals including detergents and plastics. It can also be converted into liquid fuel.
"The technology to convert carbon monoxide into liquid fuel has been around a long time," said Kubiak. "It was invented in Germany in the 1920s. The U.S. was very interested in the technology during the 1970s energy crisis, but when the energy crisis ended people lost interest. Now things have come full circle because rising fuel prices make it economically competitive to convert CO into fuel." (Interpolation: they are probably referring to the F-T process, where CO and Hydrogen are combined over a catalyst to make hydrocarbon fuels)
The device designed by Kubiak and Sathrum to split carbon dioxide utilizes a semiconductor and two thin layers of catalysts. It splits carbon dioxide to generate carbon monoxide and oxygen in a three-step process. The first step is the capture of solar energy photons by the semiconductor. The second step is the conversion of optical energy into electrical energy by the semiconductor. The third step is the deployment of electrical energy to the catalysts. The catalysts convert carbon dioxide to carbon monoxide on one side of the device and to oxygen on the other side.
Because electrons are passed around in these reactions, a special type of catalyst that can convert electrical energy to chemical energy is required Researchers in Kubiak's laboratory have created a large molecule with three nickel atoms at its heart that has proven to be an effective catalyst for this process.
Choosing the right semiconductor is also critical to making carbon dioxide splitting practical say the researchers. Semiconductors have bands of energy to which electrons are confined. Sunlight causes the electrons to leap from one band to the next creating an electrical energy potential The energy difference between the bands—the band gap—determines how much solar energy will be absorbed and how much electrical energy is generated.
Kubiak and Sathrum initially used a silicon semiconductor to test the merits of their device because silicon is well-studied. However, silicon absorbs in the infrared range and the researchers say it is "too wimpy" to supply enough energy. The conversion of sunlight by silicon supplied about half of the energy needed to split carbon dioxide, and the reaction worked if the researchers supplied the other half of the energy needed.
They are now building the device using a gallium-phosphide semiconductor. It has twice the band gap of silicon and absorbs more energetic visible light. Therefore, they predict that it will absorb the optimal amount of energy from the sun to drive the catalytic splitting of carbon dioxide.
"This project brings together many scientific puzzle pieces," said Sathrum. "Quite a bit of work has been done on each piece, but it takes more science to mesh them all together. Bringing all the pieces together is the part of the problem we are focused on."
Source: University of California - San Diego.
Technorati Tags: Energy
eerickso,eerickso said:Just to be clear, are you talking about a tank with lots of water? Warm water releases C02. So yes, I accept your results.
So with the increase of manmade CO2 and the CO2 released by the earth's water and the CO2 released by melting arctic tundra. We, as citizen of the earth, are conducting not only the world’s largest uncontrolled experiment, but also the world’s most dangerous experiment.
EU green targets will damage rainforests
By Bruno Waterfield in Brussels
Last Updated: 5:51am BST 27/04/2007
European union green fuel targets will accelerate the destruction of rainforests in South-East Asia and threaten the habitat of endangered species, such as the orang-utan.
In March EU leaders agreed to set a binding climate change target to make biofuel - energy sources made from plant material - account for 10 per cent of all Europe's transport fuels by 2020.
But the European Commission has admitted that the objective, which aims to cut carbon dioxide emissions, may have the unintended consequence of speeding up the destruction of tropical rainforests and peatlands in South-East Asia - actually increasing, not reducing, global warming.
European consumption of plant-based fuels will soar from around three million tons at present to more than 30 million tons in 2010, driving a boom in imports of cheap biofuels.
Europe is still years away from self-sufficiency in biofuels produced from straw and other waste vegetation. As a result, demand for cheap imports of fuels, such as palm oil, is expected to soar.
Countries such as Indonesia have already begun planning an increase in the production of palm oil, a development campaigners fear will see more rainforest fall to the axe and rare peat soil burned.
......
Ethanol Demand Threatens Food Prices
Rising corn prices are already affecting everything from the cost of tortillas in Mexico City to the cost of producing eggs in the United States.
The recent rise in corn prices--almost 70 percent in the past six months--caused by the increased demand for ethanol biofuel has come much sooner than many agriculture economists had expected.
According to the United States Department of Agriculture, this year the country is going to use 18 to 20 percent of its total corn crop for the production of ethanol, and by next year that will jump to 25 percent. And that increase, says Marshall Martin, an agriculture economist at Purdue University, "is the main driver behind the price increase for corn."
The jump in corn prices is already affecting the cost of food. The most notable example: in Mexico, which gets much of its corn from the United States, the price of corn tortillas has doubled in the past year, according to press reports, setting off large protest marches in Mexico City.
a_majoor said:If this development pans out, Carbon Dioxide will become a valuable raw material. Real science vs Kyoto consensus.......
http://digg.com/environment/Turning_carbon_dioxide_into_fuel_using_solar_power
(Interpolation: they are probably referring to the F-T process, where CO and Hydrogen are combined over a catalyst to make hydrocarbon fuels)
The device designed by Kubiak and Sathrum to split carbon dioxide utilizes a semiconductor and two thin layers of catalysts. It splits carbon dioxide to generate carbon monoxide and oxygen in a three-step process. The first step is the capture of solar energy photons by the semiconductor. The second step is the conversion of optical energy into electrical energy by the semiconductor. The third step is the deployment of electrical energy to the catalysts. The catalysts convert carbon dioxide to carbon monoxide on one side of the device and to oxygen on the other side.
Kirkhill said:So while we are on the subject of unintended consequences: Behold Biofuels
They are driving up ALL food prices, depriving the third world of staple foods, cattle of feed and Coca Cola of sugar and sweeteners. It will result in deforestation of the rain forest as poor countries attempt to cash in resulting in reduced carbon sinks - and the carbon of which the biofuels are made will STILL be released to the atmosphere. And to top it all off the energy-mass balance still means that it costs more energy to produce the biofuel than it produces.
http://www.telegraph.co.uk/news/main.jhtml?xml=/news/2007/04/27/wgreen27.xml
http://www.technologyreview.com/Energy/18173/
Oh, and by they way - those nifty high efficiency, low heat fluorescent light bulbs? Be prepared for your heating bills to go up when you switch to them. Those traditional incandescent light bulbs, emitting heat right where you are sitting reading, typing, watching TV, having a beer, are helping to keep you warm meaning your furnace doesn't have to run as much. Also because the heat is right where you are you can live with the thermostat a little lower in the rest of the house. Without that local heating then you will likely be raising the overall temperature of the house. That always assumes that your forced air circulation system is working well and all your vents and ducts are well placed.
As well, those lights which are supposed to reduce your lighting bill and last longer thereby justifying their additional expense - the long life only applies if you leave the light on all the time. Normal bedside use reduced the 5 year life expectancy to 1 year.
But.............we're all Green now. All Hail Gaia.
Flip said:Kirkhill - you were stealing my thoughts! - It's a conspiracy.
Brad Sallows said:I can't remember where, but some blogger posted a back-of-the-envelope calculation to support his hypothesis that there may already be enough manufacturing capacity for the new bulbs to support our requirements and that the rate of adoption is already high enough. His point is that the bulbs last so long that after the initial buying surge there will be a trough in sales for a few years while the first generation of bulbs runs down its life span. If the hypothesis is correct, we are not doing the market any favours by providing additional incentives (subsidies, bans) to increase manufacturing capacity right now. It should be self-evident that for a long-lifed replacement product, it is better to allow it to be phased in gradually. A handful of years may not be enough.
Flip said:As I've mentioned before - heat might not be so bad.
Most of us pay money to heat the house-most of the time.
If the heat doesn't come from the light bulbs it comes from somewhere else.
If you heat with electricity, the cost is the same.